第一章 緒論
分析(xi)化學:analytical chemistry
定性分析:qualitative analysis
定量分析:quantitative analysis
物理(li)分析:physical analysis
物理化(hua)學分析:physico-chemical analysis
儀器分(fen)析法:instrumental analysis
流動(dong)注射(she)分析法:flow injection analysis;FIA
順序(xu)注射分(fen)析(xi)法(fa):sequentical injection analysis;SIA
化學(xue)計量學(xue):chemometrics
第二章 誤差的分析數據處理
絕(jue)對(dui)誤差(cha):absolute error
相對誤差(cha):relative error
系統誤差:systematic error
可定(ding)誤差:determinate error
隨機誤差:accidental error
不可定(ding)誤(wu)差:indeterminate error
準(zhun)確度:accuracy
精確度:precision
偏差:debiation,d
平均偏(pian)差:average debiation
相對(dui)平均偏差:relative average debiation
標(biao)準(zhun)偏差(標(biao)準(zhun)差):standerd deviation;S
相對平均偏(pian)差(cha):relatibe standard deviation;RSD
變(bian)異(yi)系數(shu):coefficient of variation
誤差傳(chuan)遞:propagation of error
有(you)效數字:significant figure
置信水平:confidence level
顯(xian)著(zhu)性水平:level of significance
合(he)(he)并標(biao)準偏差(組(zu)合(he)(he)標(biao)準差):pooled standard debiation
舍(she)棄商:rejection quotient ;Q
化學定量分析
第三章 滴定分析概論
滴定分(fen)析(xi)法:titrametric analysis
滴定:titration
容量分析法:volumetric analysis
化學(xue)計量點:stoichiometric point
等當點:equivalent point
電(dian)荷平衡(heng):charge balance
電(dian)荷平衡式:charge balance equation
質量平衡:mass balance
物料平衡:material balance
質量平衡(heng)式:mass balance equation
第四章 酸堿滴定法
酸堿滴定法(fa):acid-base titrations
質子自遞(di)反(fan)應:autoprotolysis reaction
質子自(zi)遞常數:autoprotolysis constant
質(zhi)子條件式:proton balance equation
酸堿指示劑:acid-base indicator
指示劑常數:indicator constant
變(bian)色范圍:colour change interval
混合(he)指示劑:mixed indicator
雙指示(shi)劑滴(di)定法:double indicator titration
第五章 非水滴定法
非(fei)水滴定(ding)法:nonaqueous titrations
質子(zi)溶劑(ji):protonic solvent
酸性(xing)溶(rong)劑:acid solvent
堿性溶(rong)劑:basic solvent
兩性溶劑:amphototeric solvent
無質(zhi)子溶(rong)劑:aprotic solvent
均化效(xiao)應:differentiating effect
區(qu)分性(xing)溶劑:differentiating solvent
離子化:ionization
離解:dissociation
結晶紫(zi):crystal violet
萘(nai)酚(fen)苯甲醇: α-naphthalphenol benzyl alcohol
奎哪啶紅:quinadinered
百(bai)里酚藍:thymol blue
偶氮紫(zi):azo violet
溴酚藍(lan):bromophenol blue
第六章 配位滴定法
配位滴定法:compleximetry
乙二胺四(si)乙酸:ethylenediamine tetraacetic acid,EDTA
螯合(he)物:chelate compound
金(jin)屬指(zhi)示劑:metal lochrome indcator
第七章 氧化還原滴定法
氧化還原滴定法(fa):oxidation-reduction titration
碘量(liang)法:iodimetry
溴量法(fa):bromimetry ]
溴(xiu)量法:bromine method
鈰量法:cerimetry
高錳(meng)酸鉀法(fa):potassium permanganate method
條件(jian)電(dian)位:conditional potential
溴酸鉀法:potassium bromate method
硫酸鈰(shi)法:cerium sulphate method
偏高(gao)碘酸:metaperiodic acid
高碘酸(suan)鹽:periodate
亞(ya)硝酸(suan)鈉法:sodium nitrite method
重氮化反應:diazotization reaction
重氮化滴定法:diazotization titration
亞硝基化反應:nitrozation reaction
亞(ya)硝(xiao)基化(hua)滴(di)定法:nitrozation titration
外指示(shi)劑:external indicator
外指示劑:outside indicator
重鉻酸鉀法:potassium dichromate method
第八章 沉淀滴定法
沉淀滴定法:precipitation titration
容量滴定(ding)法:volumetric precipitation method
銀量法:argentometric method
第九章 重量分析法
重量分析法(fa):gravimetric analysis
揮發法:volatilization method
引濕(shi)水(濕(shi)存水):water of hydroscopicity
包埋(藏)水:occluded water
吸入水:water of imbibition
結晶水:water of crystallization
組(zu)成水:water of composition
液-液萃取(qu)法:liquid-liquid extration
溶劑萃(cui)取法(fa):solvent extration
反(fan)萃取:counter extraction
分配系數:partition coefficient
分配(pei)比:distribution ratio
離子對(離子締合物):ion pair
沉淀形(xing)式:precipitation forms
稱量形(xing)式(shi):weighing forms
《分析化學》下冊
儀器分析 概述
物(wu)理分析:physical analysis
物理(li)化(hua)學分析:physicochemical analysis
儀(yi)器(qi)分析:instrumental analysis
第十章 電位法及永停滴定法
電化學分析:electrochemical analysis
電解法(fa):electrolytic analysis method
電重(zhong)量(liang)法:electtogravimetry
庫侖法:coulometry
庫侖滴定法(fa):coulometric titration
電導(dao)法(fa):conductometry
電導分析法:conductometric analysis
電導滴定(ding)法(fa):conductometric titration
電位(wei)法:potentiometry
直接電(dian)位法:dirext potentiometry
電(dian)位(wei)滴定法(fa):potentiometric titration
伏安法(fa):voltammetry
極譜法:polarography
溶出法:stripping method
電流滴定法:amperometric titration
化學雙(shuang)電層:chemical double layer
相界電位:phase boundary potential
金屬(shu)電極電位:electrode potential
化學電池:chemical cell
液接界面:liquid junction boundary
原電池:galvanic cell
電解池:electrolytic cell
負極(ji):cathrode
正極(ji):anode
電池電動勢:eletromotive force
指示電極:indicator electrode
參比電極:reference electroade
標準氫電極:standard hydrogen electrode
一級參比電極:primary reference electrode
飽和甘汞電極:standard calomel electrode
銀(yin)-氯化銀(yin)電極:silver silver-chloride electrode
液接(jie)界(jie)面:liquid junction boundary
不(bu)對稱(cheng)電位:asymmetry potential
表觀PH值:apparent PH
復合PH電極:combination PH electrode
離子選擇(ze)電極(ji):ion selective electrode
敏感器:sensor
晶(jing)體電(dian)極(ji):crystalline electrodes
均相膜電(dian)極:homogeneous membrance electrodes
非均(jun)相膜(mo)電極(ji):heterog eneous membrance electrodes
非晶(jing)體電極:non- crystalline electrodes
剛性基質電極:rigid matrix electrode
流流體載動電極:electrode with a mobile carrier
氣敏電極(ji):gas sensing electrodes
酶電極(ji):enzyme electrodes
金屬(shu)氧化物(wu)半導體場效應晶體管(guan):MOSFET
離子選擇場效(xiao)應管(guan):ISFET
總離子強度調節(jie)緩沖劑(ji):total ion strength adjustment buffer,TISAB
永停滴定法(fa):dead-stop titration
雙電(dian)流滴(di)定法(fa)(雙安培滴(di)定法(fa)):double amperometric titration
第十一章 光譜分析法概論
普(pu)朗克常數:Plank constant
電磁波譜:electromagnetic spectrum
光譜:spectrum
光譜分析法:spectroscopic analysis
原子(zi)發射光譜法(fa):atomic emission spectroscopy
質(zhi)量(liang)譜:mass spectrum
質譜法:mass spectroscopy,MS
第十二章 紫外-可見分光光度法
紫外-可見分(fen)光光度法:ultraviolet and visible spectrophotometry;UV-vis
肩峰(feng):shoulder peak
末端吸收:end absorbtion
生色團:chromophore
助色(se)團:auxochrome
紅移:red shift
長移(yi):bathochromic shift
短(duan)移:hypsochromic shift
藍(紫)移(yi):blue shift
增色(se)效(xiao)應(濃色(se)效(xiao)應):hyperchromic effect
減色(se)效應(淡(dan)色(se)效應):hypochromic effect
強帶(dai):strong band
弱帶:weak band
吸收帶(dai):absorption band
透光率:transmitance,T
吸光度:absorbance
譜帶寬度:band width
雜散光:stray light
噪聲(sheng):noise
暗噪聲:dark noise
散(san)粒噪聲:signal shot noise
閃(shan)耀光柵(zha):blazed grating
全息光柵:holographic graaing
光二(er)極(ji)管陣列(lie)檢測器:photodiode array detector
偏最小(xiao)二乘(cheng)法(fa):partial least squares method ,PLS
褶(zhe)合光譜法:convolution spectrometry
褶合(he)變換:convolution transform,CT
離散小波(bo)變換:wavelet transform,WT
多尺度(du)細化(hua)分析:multiscale analysis
供(gong)電子取代基(ji):electron donating group
吸(xi)電子(zi)取代基:electron with-drawing group
第十三章 熒光分析法
熒光:fluorescence
熒光分析法(fa):fluorometry
X-射線熒光分析法:X-ray fulorometry
原(yuan)子(zi)熒(ying)光分析法:atomic fluorometry
分(fen)子熒光分(fen)析法:molecular fluorometry
振(zhen)動弛豫:vibrational relexation
內轉換(huan):internal conversion
外轉換:external conversion
體(ti)系(xi)間跨越:intersystem crossing
激發光(guang)譜:excitation spectrum
熒光光譜(pu):fluorescence spectrum
斯托克斯位移:Stokes shift
熒光壽命:fluorescence life time
熒光效率:fluorescence efficiency
熒光(guang)量子產率:fluorescence quantum yield
熒光(guang)熄滅(mie)法:fluorescence quemching method
散射光:scattering light
瑞利光:Reyleith scanttering light
拉(la)曼(man)光:Raman scattering light
第十四章 紅外分光光度法
紅外(wai)線:infrared ray,IR
中紅外(wai)吸收光譜:mid-infrared absorption spectrum,Mid-IR
遠紅外光譜:Far-IR
微波譜:microwave spectrum,MV
紅外吸收(shou)光譜(pu)法:infrared spectroscopy
紅外分(fen)光光度法:infrared spectrophotometry
振動形(xing)式:mode of vibration
伸縮振動:stretching vibration
對稱伸縮振動:symmetrical stretching vibration
不對稱(cheng)伸縮振動:asymmetrical stretching vibration
彎曲(qu)振(zhen)動:bending vibration
變(bian)形(xing)振動:formation vibration
面內彎曲振動(dong):in-plane bending vibration,β
剪式(shi)振動(dong):scissoring vibration,δ
面(mian)內搖(yao)擺(bai)振動:rocking vibration,ρ
面外(wai)彎曲振動(dong):out-of-plane bending vibration,γ
面外搖(yao)擺振動:wagging vibration,ω
蜷曲振動(dong):twisting vibration ,τ
對稱變形振(zhen)動:symmetrical deformation vibration ,δs
不對稱變形振動:asymmetrical deformation vibration, δas
特征吸收峰:charateristic avsorption band
特征頻率:characteristic frequency
相關吸(xi)收峰:correlation absorption band
雜化影響:hybridization affect
環大小(xiao)效應:ring size effect
吸收(shou)峰的強度:intensity of absorption band
環折疊振動:ring prckering vibration
第十五章 原子吸收分光光度法
原子(zi)光譜(pu)法(fa):atomic spectroscopy
原子(zi)吸收分光光度(du)法:atomic absorption spectrophotometry,AAS
原子發射分(fen)光光度法:atomic emmsion spectrophotometry,AES
原子熒光分光光度法:atomic fluorescence spectrophotometry,AFS
第十六章 核磁共振波譜法
核磁共振(zhen):nuclear magnetic resonance,NMR
核(he)磁共振波譜:NMR spectrum
核(he)磁共振波譜法:NMR spectroscopy
掃場:swept field
掃頻:seept frequency
連續波核磁共振(zhen):continuous wave NMR,CW NMR
Fourier變換(huan)NMR:PFT-NMR,FT-NMR
二(er)維核磁共振譜:2D-NMR
質子核(he)磁共振(zhen)譜:proton magnetic resonance spectrum,PMR
氫譜:1H-NMR
碳(tan)-13核(he)磁(ci)共振譜:13C-NMR spectrum,13CNMR
自旋角動量:spin angular momentum
磁旋比:magnetogyric ratio
磁量子數(shu):magnetic quantum number,m
進(jin)動:precession
弛豫(yu)歷程:relaxation mechanism
局部(bu)抗(kang)磁屏蔽:local diamagnetic shielding
屏(ping)蔽(bi)常數:shielding constant
化學位(wei)移:chemical shift
國際純粹與應(ying)用化學(xue)協會:IUPAC
磁各向異性:magnetic anisotropy
遠(yuan)程屏蔽效應:long range shielding effect
結面:nodal plane
自旋-自旋偶合:spin-spin coupling
自旋(xuan)-自旋(xuan)分裂:spin=spin splitting
單峰:singlet,s
雙(shuang)峰:doublet,d
三重峰:triplet,t
四重峰:quartet
五(wu)重(zhong)峰:quintet
六重峰:sextet
偕(xie)偶:geminal coupling
鄰偶:vicinal coupling
遠程偶(ou)合:long range coupling
磁等價:magnetic eqivalence
自旋系統:spin system
一級光(guang)譜(pu):first order spectrum
二級(ji)光譜(二級(ji)圖譜):second order spectrum
C-H光譜(pu):C-H correlated spectroscopy,C-H COSY
第十七章 質譜法
質譜分析法:mass spectrometry
質(zhi)譜(pu):mass spectrum,MS
棒圖:bar graph
選擇離子檢測:selected ion monitoring ,SIM
直接(jie)進樣(yang):direct probe inlet ,DPI
接口:interface
氣(qi)相(xiang)色譜-質譜聯用(yong):gas chromatography-mass spectrometry,GC-MS
高效液相色譜(pu)-質譜(pu)聯用(yong):high performance liquid chromatography-mass spectrometry,HPLC-MS
電子(zi)轟擊離子(zi)源:electron impact source,EI
離子峰:quasi-molecular ions
化學離子源:chemical ionization source,CI
場電離(li):field ionization,FI
場解(jie)析:field desorptiion,FD
快速原子轟擊離子源:fast stom bombardment ,FAB
質量分(fen)析器:mass analyzer
磁質譜儀:magnetic-sector mass spectrometer
四(si)(si)極(ji)桿質譜(pu)儀(yi)(四(si)(si)極(ji)質譜(pu)儀(yi)):quadrupole mass spectrometer
原子質(zhi)量(liang)單(dan)位:amu
離子豐度(du):ion abundance
相(xiang)對豐度(相(xiang)對強(qiang)度):relative avundance
基峰:base peak
質量范圍:mass range
分辨率(lv):resolution
靈敏(min)度:sensitivity
信噪比:S/N
分子離子:molecular ion
碎(sui)片離子:fragment ion
同(tong)位素離(li)子:isotopic ion
亞穩離子:metastable ion
亞穩峰:metastable peak
母(mu)離子:paren ion
子離子:daughter
含(han)奇數個電(dian)子的離子:odd electron
含偶數個電子(zi)的離子(zi):even eletron,EE
均裂:homolytic cleavage
異裂(lie)(lie)(非均裂(lie)(lie)):heterolytic cleavage
半均裂:hemi-homolysis cleavage
重排(pai):rearragement
分子量:MW
α-裂解:α-cleavage
第十八章 色譜分析法概論
色譜法(層析法):chromatography
固(gu)定相:stationary phase
流動相:mobile phase
超臨(lin)界流體(ti)色(se)譜法:SFC
高效毛細管電泳法(fa):high performance capillary electroporesis,HPEC
氣相色譜法:gas chromatography,GC
液相色(se)譜法:liquid cromatography,LC
超臨界流(liu)體色譜(pu)法:supercritical fluid chromatography,SFC
氣-固色譜法:GSC
氣-液色譜法(fa):GLC
液-固(gu)色譜法:LSC
液(ye)-液(ye)色(se)譜法(fa):LLC
柱色譜法:column chromatography
填充柱(zhu):packed column
毛(mao)細管(guan)柱:capillary column
微填充柱:icrobore packed column
高效液相色(se)譜法:high performance liquid chromatography,HPLC
平板色譜(pu)法:planar
平(ping)板色譜法:plane chromatography
紙色譜法(fa):paper chromatography
薄層色(se)譜(pu)法(fa):thin layer chromatography,TLC
薄(bo)膜色譜法;thiin film chomatography
毛(mao)細管電泳法(fa):capillary electrophoresis,CE
分(fen)配色譜法:partition chromatography
吸附色譜法:adsorpion chromaography
離子交換色譜(pu)法(fa):ion exchange chromatography,IEC
空間排阻色譜法:steric exclusion chromatography,SEC
親和色譜法:affinity chromatography
分(fen)配系(xi)數:distribution cofficient
狹義分配系(xi)數:partition coefficient
凝膠色譜法(fa):gel chromatography
凝膠滲透(tou)色(se)譜法:gel permeation chromatography,GPC
凝(ning)膠過濾色譜法:gel filtration chromatography,GFC
滲(shen)透系數:permeation coefficien;Kp
化學鍵合相(xiang)色譜法(fa):chemically bonded-phase chromatography
分(fen)配系數:distribution coefficient
靛菁綠(lv):indocyanine
氣相色(se)譜-傅立(li)葉變換(huan)紅(hong)外光譜:GC-FTIR
第十九章 經典液相色譜法
薄(bo)層(ceng)色譜(pu)法:TLC
吸附(fu):adsorption
活(huo)化:activation
脫活性:deactivation
交聯度:degree of cross linking
交換容量:exchange capacity
薄(bo)層板:thin layer plate
展開劑:developing solvent ,developer
臨界(jie)膠束濃度(du):criticak micolle concentration ,CMC
相對(dui)比移值(zhi):relative Rf, Rr
分離度:resolution ,R
分離數:separation number,SN
煅石(shi)膏:Gypsum
羧(suo)甲基纖(xian)維(wei)素鈉:CMC-Na
吸(xi)收光譜聯用:TLC-UV
薄(bo)層(ceng)色(se)譜(pu)-熒光聯(lian)用:TLC-F
薄層色譜(pu)-紅外(wai)吸收(shou)光(guang)譜(pu)聯(lian)用:TLC-IR
薄(bo)層(ceng)色譜法:TLC-MS
紙(zhi)色譜(pu)法(fa):paper chromatography
上(shang)行展開:ascending development
下行法(fa)展(zhan)開:descending development
雙向展開:two dimensional develoooment
第二十章 氣相色譜法
氣相色譜法:gas chromatography
前延峰:leading peak
拖尾峰:tailing peak
對(dui)稱因子:symmetry factor,fs
保留時間:retention time
保留體積:retention volume
死(si)時間(jian):dead time
調(diao)整保留時間:asjusted retention time
半峰寬(kuan):peak width at half height,W1/2 or Y1/2
峰寬(kuan):peak width,W
等溫線:isotherm
理論塔(ta)板高度:height equivalent to atheoretical plate
化學(xue)鍵合相:chemically bonded phase
丁二酸(suan)二乙二醇聚(ju)酯(zhi):polydiethylene glycol succinate,PDEGS,DEGS
高分子多孔(kong)微球:GDX
苯乙烯:STY
乙基乙烯苯(ben):EST
二乙(yi)烯苯:DVB
涂壁(bi)毛細(xi)管柱:wall coated open tubular column,WCOT
載體涂層毛細管柱(zhu):supprot coated open tubular column,SCOT
熱導(dao)檢測(ce)器:thermal conductivity detector,TCD
氫焰離子化檢測器:hydrogen flame ionization detector,FID
電(dian)子(zi)捕獲檢測(ce)器:electron capture detector ,ECD
噪聲:noise,N
漂移:drift,d
靈(ling)敏度:sensitivity
檢測限(敏感(gan)度):detectability,D,M
分離(li)度:resolution
歸一(yi)化(hua)法:normalization method
外標法:external standardization
第二十一章 高效液相色譜法
高效液相色譜法(fa):high performance liquid chromatography,HPLC
高(gao)速液(ye)相色譜法:high speed LC,HSLC
高壓液相色譜法:high pressure LC,HPLC
高分辨液相色(se)譜法:high resolution LC,HRLC
液固(gu)吸附色(se)譜(pu)法(fa)(液固(gu)色(se)譜(pu)法(fa)):liquid-solid adsorption chromatography,LSC
液(ye)液(ye)色譜法:liquid-liquid chromatography,LLC
正相:normal phase,NP
反相:reversed phase,RP
化學鍵合相色譜法:bonded phase chromatography,BPC
十(shi)八烷(wan)基:octadecylselyl,ODS
離(li)子對色譜法:paired ion chromatography,PIC
反相離子對(dui)色(se)譜法:RPIC
離(li)子抑制(zhi)色(se)譜(pu)法:ion suppression chromatography,ISC
離子色譜法:ion chromatography,IC
手性(xing)色譜法:chiral chromatography,CC
環糊精(jing)色譜法:cyclodextrin chromatography,CDC
膠束色譜法:micellar chromatography,MC
親和(he)色譜法(fa):affinity chromatography,AC
固(gu)定相:stationary phase
化學鍵合相:chemically bonde phase
封(feng)尾、封(feng)頂、遮(zhe)蓋:end capping
手性固定相:chiral stationary phase,CSP
恒組(zu)成溶(rong)劑洗脫:isocraic elution
梯度洗脫:gradient elution
紫外(wai)檢(jian)測器(qi):ultraviolet detector,UVD
熒(ying)光檢測器:fluorophotomeric detector,FD
電化學檢測器:ECD
示差折光檢測器:RID
光電二極管檢測器:photodiode array detector ,DAD
三維光(guang)譜(pu)-波譜(pu)圖:3D-spectrochromatogram
蒸發光散射(she)檢測(ce)器:evaporative light scattering detector,ELSD
安培檢測器:ampere detector,AD
高效毛細管電泳法:high performance capillary electrophoresis,HPCE
淌度:mobility
電泳:electrophoresis
電(dian)滲:electroosmosis
動力進樣:hydrodynamic injection
電(dian)動進樣:electrokinetic injection
毛細管區帶(dai)電(dian)泳法(fa):capillary zone electrophoresis,CZE
膠束(shu)電動毛細管色譜:micellar electrokinetic capillary chromatography,MECC
毛細管凝膠電泳:capillary gel electrophoresis,CGE
篩分:sieving
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